Product ID:1,1'-THIOBIS(BENZENE), O-949
MSDS Date:09/01/1988
FSC:6810
NIIN:00N067994
MSDS Number: CBGWM

Emergency Phone: 215-692-3026

Info Phone: 215-692-3026

Cage: 84898

Telephone: 610-692-3026

Cage: 8Y898

PHENYL SULFIDE; (1,1'-THIOBIS(BENZENE))

CAS: 139-66-2

RTECS: SX2275000

OSHA PEL N/K

ACGIH TLV: N/K

LD50 LC50 Mixture:LD50: (RAT) 490 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ALL CHEMICALS SHOULD BE CONSIDERED
HAZARDOUS - AVOID DIRECT PHYSICAL CONTACT! CAN BE FATAL IF ABSORBED
THROUGH THE SKIN! CAN BE FATAL IF INHALED! MAY BE FATAL IF
SWALLOWED! CAN CAUSE EYE IRRITATION. C AN CAUSE SKIN IRRITATION.
CAN BE HARMFUL IF ABSORBED THROUGH THE SKIN. CAN BE HARMFUL IF
INHALED. CAN (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: BE HARMFUL IF SWALLOWED. POSSIBLE
CHOLINESTERASE INHIBITOR-MAY CAUSE SEIZURES, NAUSEA, VOMITING,
AIRWAY OBSTRUCTION AND/OR INCREASED MUCOUS SECRETIONS IN THE LUNGS.
CAN BE IRRITATING TO MUCO US MEMBRANES. PROLONGED EXPOSURE MAY
CAUSE NAUSEA/HEADACHE/DIZZINESS AND/OR EYE DAMAGE.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:ANTIDOTE IS SUBSTANCE INTENDED TO COUNTERACT EFT OF POISON.
IT SHOULD BE ADMIN ONLY BY MD/TRAINED EMER PERS. MED ADVICE CAN BE
OBTAINED FROM POIS CTL CTR. EYES:FLUSH CONTINUOUSLY W/WATER FOR AT
LEAST 15-20 MIN. SKIN: FLUSH W/WATER FOR 15-20 MIN. IF NO BURNS
HAVE OCCURRED-USE SOAP & WATER TO CLEANSE SKIN. INHAL: REMOVE TO
FRESH AIR. ADMIN OXYGEN IF HAVING DFCLTY BRTHG. IF BRTHG HAS
STOPPED (SUPDAT)

Flash Point:234F,112C
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL POWDER OR WATER SPRAY.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER.

Spill Release Procedures:EVACUATE AREA. WEAR APPROPRIATE OSHA-REGULATED
EQUIPMENT. VENTILATE AREA. ABSORB ON VERMICULITE OR SIMILAR
MATERIAL. SWEEP UP AND PLACE IN AN APPROPRIATE CONTAINER. HOLD FOR
DISPOSAL. WASH CONTAMINATE D SURFACES TO REMOVE ANY RESIDUES.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:AVOID CONTACT WITH SKIN, EYES AND
CLOTHING. KEEP TIGHTLY CLOSED AND STORE IN A COOL, DRY PLACE. STORE
ONLY WITH COMPATIBLE CHEMICALS.
Other Precautions:PERSONS NOT SPECIFICALLY & PROPERLY TRAINED SHOULD
NOT HANDLE THIS CHEM OR ITS CNTNR. THIS PROD IS FURNISHED FOR LAB
USE ONLY! PRODS MAY NOT BE USED AS DRUGS, COSMETICS,
AGRICULTURAL/PESTICIDAL PRODS, FOOD ADDITIVES OR AS HOUSEHOLD
CHEMS.

Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR.
Ventilation:THIS CHEMICAL SHOULD BE HANDLED ONLY IN A HOOD.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES .
Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER . USE
APPROPRIATE OSHA/MSHA APPROVED SAFETY EQUIPMENT.
Work Hygienic Practices:CONTACT LENSES SHOULD NOT BE WORN IN THE
LABORATORY.
Supplemental Safety and Health
FIRST AID PROC: ADMIN ARTF RESP. IF IN CARD ARREST ADMIN CPR. CONTINUE
LIFE SUPPORTING MEASURES UNTIL MED ASSISTANCE HAS ARRIVED.

Boiling Pt:B.P. Text:565F,296C
Melt/Freeze Pt:M.P/F.P Text:-40F,-40C
Spec Gravity:1.118
Solubility in Water:INSOL (IMMISICIBLE)
Appearance and Odor:COLORLESS LIQUID; ODORLESS.

Stability Indicator/Materials to Avoid:YES
INCOMPATIBLE WITH STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:COMBUSTIBLE.
Hazardous Decomposition Products:DECOMPOSITION LIBERATES TOXIC FUMES.
DECOMPOSITION PRODUCTS ARE CORROSIVE.

Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH FEDERAL,
STATE AND LOCAL REGULATIONS . BURN IN A CHEMICAL INCINERATOR
EQUIPPED WITH AN AFTERBURNER AND SCRUBBER.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.